Cas no 116128-29-1 ((R)-Ru(OAc)2(T-BINAP))
(R)-Ru(OAc)2(T-BINAP) Chemical and Physical Properties
Names and Identifiers
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- Ruthenium, bis(acetato-kO,kO')[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)phosphine-kP]]-, (OC-6-22)-
- (R)-Ru(OAc)2(T-BINAP)
- Ru(OAc)2[(R)-tolbinap]
- DIACETATO[(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II)
- Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II), Ru(OAc)2[(R)-tolbinap]
- Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II),Ru(OAc)2[(R)-tolbinap]
- (S)-Ru(OAc)2(T-BINAP)
- -binaphthyl]ruthenium(II) Ru(OAc)2[(R)-tolbinap]
- -bis(di-p-tolylphosphino)-1,1'
- Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)
- Ru(O2CMe)2((R)-tolBINAP)
- Ru(OAc)2((R)-Tol-BINAP)
- Ru(OCOCH3)2((R)-tol-binap)
- -binaphthyl]ruthenium(II),Ru(OAc)2[(R)-tolbinap]
- Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-tolbinap]
- [1-[2-Bis(4-methylphenyl)phosphaniumylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphaniu
- CID 138114756
- Ruthenium(2+) acetate 1,1'-binaphthalene-2,2'-diylbis[bis(4-methy lphenyl)phosphine] (1:2:1)
- Ruthenium, bis(acetato-κO,κO')[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)phosphine-κP]]-, (OC-6-22)-
- (1-{2-[bis(4-methylphenyl)phosphanyl]naphthalen-1-yl}naphthalen-2-yl)bis(4-methylphenyl)phosphane (acetyloxy)ruthenio acetate
- 106681-15-6
- E81026
- 116128-29-1
- AKOS015908623
- RU(OAC)2[(S)-TOLBINAP]
- Diacetato[(S)-(-)-2,2/'-bis(di-p-tolylphosphino)-1,1/'-binaphthyl]ruthenium(II)
- acetic acid;[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane;ruthenium
- Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-tolbinap]
- Diacetato[(R)-(+)-2,2/'-bis(di-p-tolylphosphino)-1,1/'-binaphthyl]ruthenium(II)
-
- MDL： MFCD09753021
- Inchi： 1S/C48H40P2.2C2H4O2.Ru/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;2*1-2(3)4;/h5-32H,1-4H3;2*1H3,(H,3,4);
- InChI Key： OXESSJMVRGFBNX-UHFFFAOYSA-N
- SMILES： [Ru].P(C1C=CC(C)=CC=1)(C1C=CC(C)=CC=1)C1=CC=C2C=CC=CC2=C1C1=C2C=CC=CC2=CC=C1P(C1C=CC(C)=CC=1)C1C=CC(C)=CC=1.OC(C)=O.OC(C)=O
Computed Properties
- Exact Mass: 898.19100
- Monoisotopic Mass: 900.207124g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 4
- Heavy Atom Count: 59
- Rotatable Bond Count: 4
- Complexity: 1080
- Covalently-Bonded Unit Count: 4
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Topological Polar Surface Area: 80.3
Experimental Properties
- Color/Form: Not available
- Density: Not available
- Melting Point: >100°C
- Boiling Point: Not available
- Flash Point: Not available
- PSA: 107.44000
- LogP: 7.92240
- Solubility: Not available
- Sensitiveness: air sensitive
- Vapor Pressure: Not available
(R)-Ru(OAc)2(T-BINAP) Security Information
- Signal Word：warning
- Hazard Statement： H303+H313+H333
- Warning Statement： P264+P280+P305+P351+P338+P337+P313
- Hazardous Material transportation number：NONH for all modes of transport
- WGK Germany：3
- Safety Instruction： H303+H313+H333
- Storage Condition：2-8°C
(R)-Ru(OAc)2(T-BINAP) Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd. | 600245-1g |
(R)-Ru(OAc)2(T-BINAP) |
116128-29-1 | 95% | 1g |
￥1400.0 | 2024-07-19 | |
| SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd. | 600245-250mg |
(R)-Ru(OAc)2(T-BINAP) |
116128-29-1 | 95% | 250mg |
￥400.0 | 2024-07-19 | |
| Chemenu | CM102908-1g |
Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) |
116128-29-1 | 95% | 1g |
$280 | 2021-06-15 | |
| abcr | AB200392-250 mg |
Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II); . |
116128-29-1 | 250 mg |
€55.50 | 2023-07-20 | ||
| abcr | AB200392-1 g |
Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II); . |
116128-29-1 | 1 g |
€139.00 | 2023-07-20 | ||
| abcr | AB200392-5 g |
Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II); . |
116128-29-1 | 5 g |
€328.00 | 2023-07-20 | ||
| SHANG HAI MAI KE LIN SHENG HUA Technology Co., Ltd. | R868056-200mg |
Ru(OAc)2[(R)-tolbinap] |
116128-29-1 | 200mg |
￥398.00 | 2022-08-31 | ||
| SHANG HAI MAI KE LIN SHENG HUA Technology Co., Ltd. | R868056-1g |
Ru(OAc)2[(R)-tolbinap] |
116128-29-1 | 1g |
￥1,390.00 | 2022-08-31 | ||
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | R0168-1g |
Ru(OAc)2[(R)-tolbinap] |
116128-29-1 | 1g |
￥1530.0 | 2022-06-10 | ||
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | R0168-200mg |
Ru(OAc)2[(R)-tolbinap] |
116128-29-1 | 200mg |
￥475.0 | 2022-06-10 |
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(R)-Ru(OAc)2(T-BINAP) Related Literature
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Heidi Bernas,Andreas Bernas,P?ivi M?ki-Arvela,Reko Leino,Dmitry Yu. Murzin Catal. Sci. Technol. 2012 2 1901
Additional information on (R)-Ru(OAc)2(T-BINAP)
Comprehensive Overview of (R)-Ru(OAc)2(T-BINAP) (CAS No. 116128-29-1): Applications and Innovations in Asymmetric Catalysis
The (R)-Ru(OAc)2(T-BINAP) complex, identified by its CAS No. 116128-29-1, represents a cornerstone in the field of asymmetric catalysis. This chiral ruthenium-based catalyst, featuring the T-BINAP ligand, has garnered significant attention for its exceptional enantioselectivity and efficiency in organic transformations. Researchers and industries alike prioritize this compound for its ability to facilitate stereocontrolled reactions, particularly in pharmaceutical synthesis and fine chemical production. Its unique structural configuration, combining Ru(OAc)2 with the axially chiral BINAP derivative, enables precise control over reaction outcomes, making it indispensable for modern synthetic methodologies.
In recent years, the demand for sustainable catalysis and green chemistry solutions has surged, aligning with global trends toward environmentally friendly processes. (R)-Ru(OAc)2(T-BINAP) addresses these needs by offering high atom economy and reduced waste generation. A frequent query in scientific forums revolves around its reusability and stability under mild conditions, both of which are critical for cost-effective industrial applications. Studies confirm that this catalyst maintains activity over multiple cycles, particularly in hydrogenation and C-C bond-forming reactions, further enhancing its appeal.
The versatility of CAS No. 116128-29-1 extends to its role in pharmaceutical intermediates synthesis. For instance, it is pivotal in producing chiral amines and alcohols, key building blocks for APIs (Active Pharmaceutical Ingredients). Searches for "ruthenium catalysts for drug synthesis" or "asymmetric hydrogenation catalysts" often highlight this compound due to its compatibility with complex substrates. Its low toxicity profile compared to other heavy-metal catalysts also aligns with stringent regulatory requirements, a topic frequently explored in AI-driven drug discovery discussions.
From a technical perspective, the T-BINAP ligand in (R)-Ru(OAc)2(T-BINAP) introduces steric and electronic tunability, enabling selective substrate recognition. This feature is particularly valuable for dynamic kinetic resolution (DKR), a process widely searched in academic databases. The catalyst's performance in DKR underscores its potential to streamline the synthesis of enantiopure compounds, reducing the need for costly purification steps. Moreover, its air stability and ease of handling make it a preferred choice for both academic labs and industrial-scale operations.
Emerging trends in computational chemistry have further amplified interest in 116128-29-1. Molecular modeling studies frequently cite this complex to validate predictive algorithms for enantioselectivity, bridging theoretical and experimental chemistry. Such interdisciplinary applications resonate with searches like "AI in catalyst design" or "machine learning for asymmetric synthesis." This synergy positions (R)-Ru(OAc)2(T-BINAP) as a model system for future catalyst development.
In conclusion, (R)-Ru(OAc)2(T-BINAP) (CAS No. 116128-29-1) stands at the intersection of innovation and practicality. Its robust performance in chiral synthesis, alignment with green chemistry principles, and adaptability to cutting-edge technologies ensure its relevance in evolving scientific landscapes. As research continues to explore its full potential, this catalyst remains a focal point for advancements in precision chemistry and industrial applications.
116128-29-1 ((R)-Ru(OAc)2(T-BINAP)) Related Products
- 76189-56-5((S)-BINAP)
- 374067-49-9(Ruthenium, bis(acetato-kO,kO')[(1S)-[1,1'-binaphthalene]-2,2'-diylbis[bis(3,5-dimethylphenyl)phosphine-kP]]-, (OC-6-22)- (9CI))
- 76189-55-4((R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)
- 100165-88-6((S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl)
- 153305-67-0(2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL)
- 106681-15-6((S)-Ru(OAc)2(T-binap))
- 98327-87-8(1.1'-Binaphthyl-2.2'-diphemyl phosphine)
- 374067-50-2([1-[2-bis(3,5-dimethylphenyl)phosphanyl-1-naphthyl]-2-naphthyl]-bis(3,5-dimethylphenyl)phosphane;ruthenium(2+);diacetate)
- 261948-85-0((S)-Ru(OAc)2(BINAP))
- 99646-28-3((R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl)
