Cas no 1133-80-8 (2-Bromofluorene)
2-Bromofluorene (CAS 1133-80-8) is a brominated derivative of fluorene, featuring a bromine atom at the 2-position of the aromatic ring. This compound serves as a versatile intermediate in organic synthesis, particularly in the preparation of pharmaceuticals, agrochemicals, and functional materials. Its high reactivity in cross-coupling reactions, such as Suzuki and Buchwald-Hartwig couplings, makes it valuable for constructing complex molecular architectures. The bromine substituent enhances its utility in nucleophilic substitution and metal-catalyzed transformations. With a well-defined crystalline structure and stability under standard conditions, 2-Bromofluorene is a reliable building block for research and industrial applications requiring precise functionalization of the fluorene scaffold.
2-Bromofluorene structure
Product Name:2-Bromofluorene
CAS No:1133-80-8
MF:C13H9Br
MW:245.114562749863
MDL:MFCD00001115
CID:40890
PubChem ID:14336
Update Time:2025-07-02
2-Bromofluorene Chemical and Physical Properties
Names and Identifiers
-
- 2-Bromofluorene
- 2-bromo-9h-fluorene
- 2-Bromofluorene, Pract.
- 2-Bromofluorene, Tech.
- 4-Bromo-2,2'-methylenebiphenyl
- 2-BroMofluorene, BroMofluorene
- 2-bromidefluorene
- 2-Brom-fluoren
- 2-bromo-fluorene
- 2-fluorenylbromide
- FD14012
- 9H-Fluorene, 2-bromo-
- AKOS015835445
- MFCD00001115
- DTXSID00150357
- 2-Bromo-9H-fluorene #
- DS-1100
- UNII-J2DF3P68J2
- EN300-217267
- NSC1463
- 2-brom-9H-fluoren
- AM20060920
- AI3-00816
- CS-W010255
- Q-101150
- SCHEMBL415882
- A15135
- NSC-1463
- EINECS 214-480-6
- 9H-Fluorene,2-bromo
- 1133-80-8
- BCP27073
- FT-0611561
- NS00015767
- 2-Bromofluorene, 95%
- NSC 1463
- B3069
- InChI=1/C13H9Br/c14-11-5-6-13-10(8-11)7-9-3-1-2-4-12(9)13/h1-6,8H,7H
- J2DF3P68J2
- SY004751
- 2-Bromo-9H-fluorene; NSC 1463
- DB-027895
-
- MDL： MFCD00001115
- Inchi： 1S/C13H9Br/c14-11-5-6-13-10(8-11)7-9-3-1-2-4-12(9)13/h1-6,8H,7H2
- InChI Key： FXSCJZNMWILAJO-UHFFFAOYSA-N
- SMILES： BrC1C=CC2C3C=CC=CC=3CC=2C=1
- BRN： 1946701
Computed Properties
- Exact Mass: 243.98900
- Monoisotopic Mass: 243.989
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 14
- Rotatable Bond Count: 0
- Complexity: 213
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- Tautomer Count: nothing
- XLogP3: nothing
- Topological Polar Surface Area: 0A^2
Experimental Properties
- Color/Form: Crystalline powder
- Density: 1.4187 (rough estimate)
- Melting Point: 112-114?°C (lit.)
- Boiling Point: 185?°C/135?mmHg(lit.)
- Flash Point: 185℃/135mm
- Refractive Index: 1.6290 (estimate)
- Solubility: Soluble in chloroform and ethyl acetate.
- PSA: 0.00000
- LogP: 4.02030
- Solubility: Insoluble
2-Bromofluorene Security Information
-
Symbol:
- Prompt：warning
- Signal Word：Warning
- Hazard Statement： H315,H319,H335
- Warning Statement： P261,P305+P351+P338
- Hazardous Material transportation number：NONH for all modes of transport
- WGK Germany：3
- Hazard Category Code： 36/37/38
- Safety Instruction： S26-S37/39
-
Hazardous Material Identification：
- Safety Term：S26;S37/39
- Risk Phrases：R36/37/38
- HazardClass：IRRITANT
- Storage Condition：Sealed in dry,Room Temperature
2-Bromofluorene Customs Data
- HS CODE：2903999090
- Customs Data：
China Customs Code:
2903999090Overview:
2903999090 Other aromatic halogenated derivatives. VAT:17.0% Tax refund rate:9.0% Regulatory conditions:nothing MFN tariff:5.5% general tariff:30.0%
Declaration elements:
Product Name, component content, use to
Summary:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
2-Bromofluorene Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B3069-5g |
2-Bromofluorene |
1133-80-8 | 98.0%(GC) | 5g |
￥80.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B3069-100g |
2-Bromofluorene |
1133-80-8 | 98.0%(GC) | 100g |
￥640.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B3069-25g |
2-Bromofluorene |
1133-80-8 | 98.0%(GC) | 25g |
￥210.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B452A-100g |
2-Bromofluorene |
1133-80-8 | 97% | 100g |
￥229.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B452A-5g |
2-Bromofluorene |
1133-80-8 | 97% | 5g |
￥32.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B452A-25g |
2-Bromofluorene |
1133-80-8 | 97% | 25g |
￥64.0 | 2022-05-30 | |
| Fluorochem | 005331-1g |
2-Bromofluorene |
1133-80-8 | 97% | 1g |
￡10.00 | 2022-03-01 | |
| Fluorochem | 005331-5g |
2-Bromofluorene |
1133-80-8 | 97% | 5g |
￡10.00 | 2022-03-01 | |
| Fluorochem | 005331-10g |
2-Bromofluorene |
1133-80-8 | 97% | 10g |
￡17.00 | 2022-03-01 | |
| Fluorochem | 005331-25g |
2-Bromofluorene |
1133-80-8 | 97% | 25g |
￡19.00 | 2022-03-01 |
2-Bromofluorene Suppliers
Suzhou Senfeida Chemical Co., Ltd
Gold Member
Audited Supplier
(CAS:1133-80-8)2-Bromofluorene
Order Number:sfd12520;1635724
Stock Status:in Stock
Quantity:200kg/Company Customization
Purity:99.9%/98%
Pricing Information Last Updated:Friday, 19 July 2024 14:36
Price ($):discuss personally
Email:[email protected]
Amadis Chemical Company Limited
Gold Member
Audited Supplier
(CAS:1133-80-8)2-Bromofluorene
Order Number:A15135
Stock Status:in Stock
Quantity:1kg
Purity:99%
Pricing Information Last Updated:Monday, 2 September 2024 16:00
Price ($):202.0
Email:[email protected]
Tiancheng Chemical (Jiangsu) Co., Ltd
Gold Member
Audited Supplier
(CAS:1133-80-8)2-Bromofluorene
Order Number:LE17872;LE1635724
Stock Status:in Stock
Quantity:25KG,200KG,1000KG
Purity:99%
Pricing Information Last Updated:Friday, 20 June 2025 12:17
Price ($):discuss personally
Email:[email protected]
2-Bromofluorene Related Literature
-
Xu Zhang,Sarra Ben Hassine,Nicolas Richy,Olivier Mongin,Mireille Blanchard-Desce,Frédéric Paul,Christine O. Paul-Roth New J. Chem. 2020 44 4144
-
Stephan Hug,Maria B. Mesch,Hyunchul Oh,Nadine Popp,Michael Hirscher,Jürgen Senker,Bettina V. Lotsch J. Mater. Chem. A 2014 2 5928
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Dong Kyun You,Hyunhee So,Chan Hee Ryu,Mingi Kim,Kang Mun Lee Chem. Sci. 2021 12 8411
-
Imen Smari,Liqin Zhao,Kedong Yuan,Hamed Ben Ammar,Henri Doucet Catal. Sci. Technol. 2014 4 3723
-
Elba Xochitiotzi-Flores,Arturo Jiménez-Sánchez,Héctor García-Ortega,Nuria Sánchez-Puig,Margarita Romero-ávila,Rosa Santillan,Norberto Farfán New J. Chem. 2016 40 4500
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