Production Method 1

1941-30-6

1003575-43-6

819058-34-9

Reaction Conditions

1.1 Reagents: Pyridine ,  Sulfur trioxide-pyridine Solvents: Dichloromethane ;  18 h, rt; 1 h, 40 °C
1.2 1 h, rt
2.1 Catalysts: Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydiiridium ,  4,4′-Dimethoxy-2,2′-bipyridine Solvents: 1,4-Dioxane ;  36 h, 60 °C
2.2 Reagents: Hydrochloric acid Solvents: Water ;  1 h, pH 1 - 2, 60 °C → rt

Reference

Para-Selective, Iridium-Catalyzed C-H Borylations of Sulfated Phenols, Benzyl Alcohols, and Anilines Directed by Ion-Pair Electrostatic Interactions

Montero Bastidas, Jose R.; et al, Journal of the American Chemical Society, 2019, 141(39), 15483-15487

Production Method 2

13010-31-6

73183-34-3

1003575-43-6

819058-34-9

Reaction Conditions

1.1 Catalysts: Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydiiridium ,  4,4′-Dimethoxy-2,2′-bipyridine Solvents: 1,4-Dioxane ;  36 h, 60 °C
1.2 Reagents: Hydrochloric acid Solvents: Water ;  1 h, pH 1 - 2, 60 °C → rt

Reference

Para-Selective, Iridium-Catalyzed C-H Borylations of Sulfated Phenols, Benzyl Alcohols, and Anilines Directed by Ion-Pair Electrostatic Interactions

Montero Bastidas, Jose R.; et al, Journal of the American Chemical Society, 2019, 141(39), 15483-15487

3-Amino-4-fluorophenylboronic Acid Pinacol Ester Raw materials

• 1-Propanaminium,N,N,N-tripropyl-
• Tetrapropylammonium bromide
• Bis(pinacolato)diborane

3-Amino-4-fluorophenylboronic Acid Pinacol Ester Preparation Products

• 3-Amino-4-fluorophenylboronic Acid Pinacol Ester (1003575-43-6)
• 2-Fluoro-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline (819058-34-9)

• 1. Examination of the hydrogen-bonding networks in small water clusters (n = 2–5, 13, 17) using absolutely localized molecular orbital energy decomposition analysis?
  Erika A. Cobar,Paul R. Horn,Robert G. Bergman,Martin Head-Gordon Phys. Chem. Chem. Phys., 2012,14, 15328-15339
• 2. Fast-pulsing NMR techniques for the detection of weak interactions: successful natural abundance probe of hydrogen bonds in peptides?
  Amandine Altmayer-Henzien,Valérie Declerck,David J. Aitken,Ewen Lescop,Denis Merlet,Jonathan Farjon Org. Biomol. Chem., 2013,11, 7611-7615
• 3. Evolution of shape, size, and areal density of a single plane of Si nanocrystals embedded in SiO2 matrix studied by atom probe tomography
  Bin Han,Yasuo Shimizu,Gabriele Seguini,Celia Castro,Gérard Ben Assayag,Koji Inoue,Yasuyoshi Nagai,Sylvie Schamm-Chardon,Michele Perego RSC Adv., 2016,6, 3617-3622
• 4. Embedding heteroatoms: an effective approach to create porphyrin-based functional materials
  Norihito Fukui,Keisuke Fujimoto,Hideki Yorimitsu,Atsuhiro Osuka Dalton Trans., 2017,46, 13322-13341
• 5. Fatty acid eutectic mixtures and derivatives from non-edible animal fat as phase change materials?
  Pau Gallart-Sirvent,Marc Martín,Gemma Villorbina,Mercè Balcells,Aran Solé,Luisa F. Cabeza,Ramon Canela-Garayoa RSC Adv., 2017,7, 24133-24139

• Other Chemical Reagents Derivatization Reagents
• Solvents and Organic Chemicals Organic Compounds Acids/Esters

• 1269233-00-2(2,5-difluoro-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline)
• 939968-08-8(2,6-difluoro-4-(tetramethyl-1,3,2-dioxaborolan-2-yl)aniline)
• 939807-75-7(4-Amino-2,5-Difluorobenzeneboronic Acid Pinacol Ester)
• 1012880-11-3(2-Fluoro-4-methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline)
• 819057-45-9(3-Fluoro-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline)
• 819058-34-9(2-Fluoro-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline)
• 1428329-75-2(2-Fluoro-N-methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline)
• 214360-58-4(4-Fluorophenylboronic acid, pinacol ester)
• 863578-24-9(2-Amino-5-Fluorophenyl Boronic Acid Pinacol Ester)
• 1309982-16-8(5-Fluoro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzenamine)