Chloride-catalyzed, multicomponent self-assembly of arsenic thiolates?
Chemical Communications Pub Date: 2013-11-01 DOI: 10.1039/C3CC47093H
Abstract
We present the observation that chloride serves as a simple catalyst for the acceleration of a self-assembly reaction between AsCl3 and dithiolate ligands (H2L) to form As2L3 assemblies. Studies on a model monomeric arsenic complex suggest that chloride may accelerate ligand exchange dynamics in pnictogen thiolates in general.
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Journal Name：Chemical Communications
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