Chemiluminescent self-reported unfolding of single-chain nanoparticles?
Chemical Communications Pub Date: 2021-04-20 DOI: 10.1039/D1CC00068C
Abstract
We demonstrate the light-induced, crosslinker mediated collapse of linear polymer chains into single-chain nanoparticles (SCNPs) capable of self-reporting their unfolding. The crosslinker entails a phenyloxalate motif allowing for the targeted degradation of the SCNPs via addition of hydrogen peroxide that triggers chemiluminescence (CL). The time-dependant CL emission can serve as a guide to follow the time dependent unfolding of the SCNPs, allowing for a qualitative assessment of the underlying mechanism.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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