Cobalt-catalyzed carboxylation of aryl and vinyl chlorides with CO2?
Chemical Communications Pub Date: 2020-10-28 DOI: 10.1039/D0CC06451C
Abstract
The transition-metal-catalyzed carboxylation of aryl and vinyl chlorides with CO2 is rarely studied, and has been achieved only with a Ni catalyst or combination of palladium and photoredox. In this work, the cobalt-catalyzed carboxylation of aryl and vinyl chlorides and bromides with CO2 has been developed. These transformations proceed under mild conditions and exhibit a broad substrate scope, affording the corresponding carboxylic acids in good to high yields.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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