Cerium photocatalyzed radical smiles rearrangement of 2-aryloxybenzoic acids?
RSC Advances Pub Date: 2021-07-21 DOI: 10.1039/D1RA04130D
Abstract
We report herein a cerium photocatalyzed aryl migration from an aryl ether to a carboxylic acid group through radical-Smiles rearrangement. This operationally simple protocol utilizes inexpensive CeCl3 as a photocatalyst and converted a variety of 2-aryloxybenzoic acids into aryl-2-hydroxybenzoates in good yields.
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Journal Name：RSC Advances
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CAS no.: 89640-58-4
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