A convenient access to allylic triflones with allenes and triflyl chloride in the presence of (EtO)2P(O)H?

Chemical Communications Pub Date: 2019-05-30 DOI: 10.1039/C9CC03096D

Abstract

A simple method for the preparation of allylic triflones from allenes and triflyl chloride in the presence of (EtO)2P(O)H has been developed. The features of this reaction are catalyst-free and simple starting substrates. This method tolerates diverse functional groups and substituted allylic triflones are obtained in moderate to good yields.

Graphical abstract: A convenient access to allylic triflones with allenes and triflyl chloride in the presence of (EtO)2P(O)H
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