A crown-like heterometallic unit as the building block for a 3D In–Ge–S framework?
Dalton Transactions Pub Date: 2015-10-13 DOI: 10.1039/C5DT03556B
Abstract
Supertetrahedral clusters are the most common building blocks in constructing Group 13/14/16 microporous metal chalcogenide materials while other types of clusters are yet scarcely explored. Herein, a new crown-like building unit [In3Ge3S16] has been obtained. The units assemble into a 3D framework [C6H14NO]4[In6Ge3S17]·1.5H2O (1) via a dual-connection mode and a SrSi2 (srs)-type topology could be achieved by treating each unit as a tri-connected node.
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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