“Governing initiation-supporting termination” in chiral poly(n-hexyl isocyanate)?

Chemical Communications Pub Date: 2011-10-21 DOI: 10.1039/C1CC14927J

Abstract

Poly(n-hexyl isocyanate) (PHIC) with varying molecular weights were synthesized using a chiral initiator and chiral terminator by living anionic polymerization. In such PHICs, chirality of the initiator plays a decisive role in determining the helical sense of the entire polymeric chain, whereas chirality of the terminator plays a supportive role.

Graphical abstract: “Governing initiation-supporting termination” in chiral poly(n-hexyl isocyanate)
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