Both [2+2] and [2+4] additions of inert aromatics via identical ternary host–guest complexes?

Chemical Communications Pub Date: 2010-04-22 DOI: 10.1039/C003191G

Abstract

A self-assembled coordination cage enables inert aromatics to undergo both [2+2] and [2+4] cycloadditions by encapsulating them within the cavity. Aceanthrylene reacts with a maleimide derivative under thermal and photo-irradiation conditions to give a product as a single regio- and stereoisomer.

Graphical abstract: Both [2+2] and [2+4] additions of inert aromatics via identical ternary host–guest complexes
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