Catalytic cross-dimerisation giving reactive borylated polyenes toward cross-coupling?
Chemical Communications Pub Date: 2019-08-16 DOI: 10.1039/C9CC05930J
Abstract
A series of borylated conjugated trienes and skipped dienes is prepared by Ru-catalysed cross-dimerisation using alkynyl-, dienyl-, and vinyl boronates. These products are used as synthetic building blocks for polyene substructures by subsequent Pd-catalysed cross-coupling in a one-pot vessel without deprotection.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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