Catalytic and regiospecific extradiol cleavage of catechol by a biomimetic iron complex?
Chemical Communications Pub Date: 2013-09-10 DOI: 10.1039/C3CC44124E
Abstract
An iron(III)–catecholate complex of a facial tridentate ligand reacts with dioxygen in the presence of ammonium acetate–acetic acid buffer to cleave the aromatic C–C bond of 3,5-di-tert-butylcatechol regiospecifically resulting in the formation of an extradiol product with multiple turnovers.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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