Carbonylative coupling of N-chloroamines with alcohols: synthesis of esterification reagents?
Organic & Biomolecular Chemistry Pub Date: 2018-03-26 DOI: 10.1039/C8OB00462E
Abstract
Herein we report a new method for the carbonylative synthesis of carbamates. Starting from N-chloroamines and alcohols, with copper or Pd/C as the catalyst, the corresponding carbamates were produced in moderate to good yields. No additional oxidant or base is needed in this system. Notably, the produced benzotriazole-carboxylates can be used as esterification reagents.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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