Carbonylative coupling of aryl tosylates/triflates with arylboronic acids under CO atmosphere?
RSC Advances Pub Date: 2016-09-12 DOI: 10.1039/C6RA14678C
Abstract
The carbonylative Suzuki–Miyaura reaction between aryl tosylates/triflates with arylboronic acid is herein reported, using base-free conditions and a balloon pressure of carbon monoxide. Under these conditions, unsymmetrical biaryl ketones were obtained in modest to excellent yields. This method was adapted to the synthesis of oxybenzone and ketoprofen in good yields under mild conditions.
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Journal Name：RSC Advances
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CAS no.: 89640-58-4
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