Assembly of a unique octa-nuclear copper cluster-based metal–organic framework with highly selective CO2 adsorption over N2 and CH4?

Chemical Communications Pub Date: 2013-10-15 DOI: 10.1039/C3CC47462C

Abstract

By using 4-(pyrimidin-5-yl) benzoic acid (4-PmBC) as a ligand, a porous metal–organic framework based on unique octa-nuclear copper clusters was constructed, which exhibited highly selective CO2 uptake over N2 and CH4.

Graphical abstract: Assembly of a unique octa-nuclear copper cluster-based metal–organic framework with highly selective CO2 adsorption over N2 and CH4
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