Application of Pauson–Khand reaction in the total synthesis of terpenes
RSC Advances Pub Date: 2021-11-29 DOI: 10.1039/D1RA05673E
Abstract
The Pauson–Khand reaction (PKR) is a formal [2 + 2 + 1] cycloaddition involving an alkyne, an alkene and carbon monoxide mediated by a hexacarbonyldicobaltalkyne complex to yield cyclopentenones in a single step. This versatile reaction has become a method of choice for the synthesis of cyclopentenone and its derivatives since its discovery in the early seventies. The aim of this review is to point out the applications of PKR in the total synthesis of terpenes.
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Journal Name：RSC Advances
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CAS no.: 89640-58-4
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