Clean Ar–Me conversion to Ar-aldehyde with the aid of carefully designed metallocorrole photocatalysts?
Photochemical & Photobiological Sciences Pub Date: 2020-07-14 DOI: 10.1039/D0PP00218F
Abstract
Toluene, p-xylene and mesitylene were cleanly converted to their corresponding monoaldehydes via mild photooxygenation utilizing transition metal and main group β-CF3-substituted corroles. Aldehyde yield increased as more electron-donating CH3 groups are present on the substrate. 4-P was most efficient (TON ～ 1072, mesitylene) via the singlet oxygen vis the superoxide mechanism.
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Journal Name：Photochemical & Photobiological Sciences
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CAS no.: 89640-58-4
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