Lipase-mediated stereodivergent synthesis of both enantiomers of 4-(2,6-dimethylheptyl)benzoic acid
Mendeleev Communications Pub Date: DOI: 10.1070/MC1998v008n01ABEH000890
Abstract
(S)- and (R)-Enantiomers of methyl 4-(3-hydroxy-2-methylpropyl)benzoate, obtained by enzymatic kinetic resolution of the related racemic arene(tricarbonyl)chromium complex in the vinyl acetate-PPL/;Et
2
O acylating system, have been converted in four steps into the (R)- and (S)-enantiomers of the title acid, respectively.
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Journal Name:Mendeleev Communications
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CAS no.: 89640-58-4