Recyclisation of 2-amino- and 2-methylamino-2-trifluoromethyl-5,5-dimethyl-tetrahydro-4-pyrone oximes to 5-amino- and 5-methyla
Mendeleev Communications Pub Date: DOI: 10.1070/MC1999v009n01ABEH001049
Abstract
The reactions of hydroxylamine with 2-amino- and 2-methylamino-2-trifluoromethyl-5,5-dimethyltetrahydro-4-pyrones yield 2-amino- and 2-methylamino-2-trifluoromethyl-5,5-dimethyltetrahydro-4-pyrone oximes, which can be converted to 5-amino- and 5-methyl-amino-5-trifluoromethyl-3-(2-hydroxy-1,1-dimethylethyl)-Δ2-isoxazolines, respectively, by heating in ethanol.
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Journal Name:Mendeleev Communications
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CAS no.: 89640-58-4