Kinetic isotope effects in the activation of H–H bonds by palladium clusters

Mendeleev Communications Pub Date: DOI: 10.1070/MC1999v009n04ABEH001094

Abstract

The mechanism of oxidative dihydrogen addition to palladium clusters has been analysed in terms of the reaction-path Hamiltonian approximation, and the abnormal H/D kinetic isotope effect has been explained.

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