Xenon difluoride–trimethylsilyl isocyanate–triflic acid as a new system for the amination of aromatic compounds

Mendeleev Communications Pub Date: DOI: 10.1070/MC2001v011n05ABEH001514

Abstract

In the title system, OCNXeOSO2CF3 is formed, which readily oxidises iodobenzene to [PhI+–NCO OTf]. The direct amination of aromatic substrates is possible with the use of XeF2–Me3SiNCO–CF3SO3H.

Recommended Literature