Enolates of 17,20:20,21-bismethylenedioxyprednisone
Journal of the Chemical Society D: Chemical Communications Pub Date: DOI: 10.1039/C29690001497
Abstract
The factors governing enol anion formation from 17,20:20,21-bismethylenedioxyprednisone (prednisone BMD) at C-6 and C-9 have been investigated by quenching with benzoic anhydride; kinetically controlled enolisation occurs at C-6 followed by rearrangement, catalysed by unenolised ketone, to the C-9 anion.
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Journal Name：Journal of the Chemical Society D: Chemical Communications
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CAS no.: 89640-58-4
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