Competition between neighbouring-group participation by carbonyl groups and carbon acids in ester hydrolyses
Journal of the Chemical Society D: Chemical Communications Pub Date: DOI: 10.1039/C29700001315
Abstract
The alkaline hydrolyses of methyl 8-acyl- and 8-aroyl-1-naphthoates have been examined: intramolecular catalysis by the neighbouring carbonyl group occurs for the 8-formyl and 8-(3′- and 4′-substituted benzoyl)esters; whereas, the 8-acetyl, 8-propionyl, and 8-iso-butyryl esters display catalysis by the neighbouring carbon acid.
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Journal Name：Journal of the Chemical Society D: Chemical Communications
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CAS no.: 89640-58-4
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