Synthesis of 18α-fernane derivatives. A Backbone rearrangement of pentacyclic triterpenes
Journal of the Chemical Society D: Chemical Communications Pub Date: DOI: 10.1039/C29700001488
Abstract
Acid-catalysed deacetylation and rearrangement of an 11-oxo-γ-onocerin derivative are accompanied by inversion of the configuration at C-18, giving a conjugated ketone, the structure of which is proved by converting it into hopene-II.
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Journal Name：Journal of the Chemical Society D: Chemical Communications
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CAS no.: 89640-58-4
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