The reaction of benzoyl isothiocyanate with hydrazine derivatives. Part I. Reaction with some alkyl hydrazines

Journal of the Chemical Society C: Organic Pub Date: DOI: 10.1039/J39670000092

Abstract

It has been found that the reaction of benzoyl isothiocyanate with alkyl hydrazines provides a useful method for the synthesis of 1-alkyl-3-phenyl-Δ3-1,2,4-triazoline-5-thiones. Methyl hydrazine and benzyl hydrazine formed additional products as a result of a competing benzoylation reaction. The identities of the products from these reactions have been proved by independent syntheses.

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