Allylfurans
Journal of the Chemical Society C: Organic Pub Date: DOI: 10.1039/J39690001456
Abstract
Allylic iodides react with silver trichloroacetate in the presence of furans of form allyfurans in up to 40% yield in a general reaction. In contrast prop-2-ynyl iodide gave methyl 5-prop-2-ynyl-3-furoate (9) from methyl 3-furoate (1) in ca. 1% yield. A hydroxymethyl group attached to C-3 favours substitution at C-2 rather than C-5, whereas a methoxycarbonyl group exerts the reverse orientational effect.
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Journal Name：Journal of the Chemical Society C: Organic
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CAS no.: 89640-58-4
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