Reduction of thebaine with mixed hydride reducing agents
Journal of the Chemical Society C: Organic Pub Date: DOI: 10.1039/J39690001945
Abstract
Reduction of thebaine with lithium aluminium hydride–aluminium chloride mixtures gives either thebainone-A enol methyl ether or neodihydrothebaine as the major product, depending on the ratio used. A novel product, isometathebainone enol methyl ether, has been isolated from the reduction with aluminium hydride, and its structure has been confirmed by conversion into dihydrometathebainone.
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Journal Name：Journal of the Chemical Society C: Organic
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CAS no.: 89640-58-4
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