Anodic oxidation. Part VIII. Electrolysis of dimethyl sodiomalonate in hexamethylphosphoric triamide
Journal of the Chemical Society C: Organic Pub Date: DOI: 10.1039/J39700001153
Abstract
Electrolysis of dimethyl sodiomalonate in hexamethylphosphoric triamide gives tetramethyl ethane-1,1,2,2-tetracarboxylate, tetramethyl propane-1,1,3,3-tetracarboxylate, and hexamethyl propane-1,1,2,2,3,3-hexacarboxylate. Degradation of the solvent to pentamethylphosphoric triamide occurs; mechanisms for the loss of the N-methyl group and for its subsequent incorporation into the second of the above products are discussed.
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Journal Name：Journal of the Chemical Society C: Organic
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CAS no.: 89640-58-4
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