Hydride ion transfer in oxidations of alcohols and ethers
Journal of the Chemical Society B: Physical Organic Pub Date: DOI: 10.1039/J29670000205
Abstract
The rates of oxidation of various alcohols and ethers by bromine, permanganate, and mercury(II) have been measured. The observed easy oxidative fission of di-isopropyl ether, and the large accelerating effects of alkyl substituents, support mechanisms involving hydride ion transfer from the carbon atom bearing the functional group to the oxidant. Selective oxidation of an isopropyl ether function in the presence of a primary alcohol has been demonstrated.
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Journal Name：Journal of the Chemical Society B: Physical Organic
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CAS no.: 89640-58-4
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