The mechanism of the hydrolysis of glycofuranosides
Journal of the Chemical Society B: Physical Organic Pub Date: DOI: 10.1039/J29670000185
Abstract
The mechanism of the acid-catalysed hydrolysis of a series of aldofuranosides has been investigated. These reactions are shown to involve glycosyl–oxygen fission and an initial rapid proton-transfer. The entropies of activation, which are all negative, are interpreted in terms of either a bimolecular displacement of MeOH or EtOH by H2O, or a mechanism involving ring-opening.
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Journal Name：Journal of the Chemical Society B: Physical Organic
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CAS no.: 89640-58-4
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