Photolysis of perfluoro-alicyclic ketones
Journal of the Chemical Society B: Physical Organic Pub Date: DOI: 10.1039/J29690000201
Abstract
Photolysis in the gas phase of perfluorocyclo-pentanone, -hexanone, -heptanone, and -octanone at 3130 ? is reported. Migration of fluorine atoms is not observed, and in the case of the pentanone and hexanone, the only products observed were carbon monoxide and a cyclic fluorocarbon. From perfluorocycloheptanone, perfluorocyclohexane, carbon monoxide, perfluorocyclopentane, and tetrafluoroethylene were the photolysis products. Photolysis of the perfluorocyclo-octanone gave rise to perfluorocycloheptane, carbon monoxide, perfluorocyclohexane, perfluorocyclopentane, and tetrafluoroethylene. A mechanism involving diradical intermediates is proposed.
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Journal Name：Journal of the Chemical Society B: Physical Organic
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CAS no.: 89640-58-4
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