Structure of the complex of palladium(II) chloride with 1,2-bis(isopropylseleno)ethane
Journal of the Chemical Society A: Inorganic, Physical, Theoretical Pub Date: DOI: 10.1039/J19700000113
Abstract
Three-dimensional single-crystal X-ray studies of the complex of palladium(II) chloride with 1,2-bis(isopropylseleno)ethane confirms that crystals from acetone are monomeric. The space group is P21/c with Z= 4 in a unit cell of dimensions a= 8·38, b= 8·97, c= 18·67 ?, and β= 95·7°. The palladium, two chlorine and two selenium atoms are coplanar. The isopropyl groups both lie on the same side of this plane and the chelate ring has a gauche conformation about the C–C bond. Isotropic least-squares refinement of the structure of PdCl2Se2C8H18 gave R 0·12 for 857 observed reflections.
Recommended Literature
- [1] An arsenic trioxide nanoparticle prodrug (ATONP) potentiates a therapeutic effect on an aggressive hepatocellular carcinoma model via enhancement of intratumoral arsenic accumulation and disturbance of the tumor microenvironment? Xin Fu,Qing-rong Liang,Rong-guang Luo,Yan-shu Li,Xiao-ping Xiao,Lu-lu Yu,Wen-zhe Shan,Guang-qin FanJ. Mater. Chem. B, 2019,7, 3088-3099 10.1039/C9TB00349E
- [2] Always a matter of interpretation: inferring student knowledge and understanding from research data Chem. Educ. Res. Pract., 2017,18, 7-12 10.1039/C6RP90012G
- [3] An astrophysically-relevant mechanism for amino acid enantiomer enrichment Stephen P. Fletcher,Richard B. C. Jagt,Ben L. FeringaChem. Commun., 2007, 2578-2580 10.1039/B702882B
- [4] An asymmetric supercapacitor based on controllable WO3 nanorod bundle and alfalfa-derived porous carbon? Kanjun Sun,Fengting Hua,Shuzhen Cui,Yanrong Zhu,Hui Peng,Guofu MaRSC Adv., 2021,11, 37631-37642 10.1039/D1RA04788D
- [5] An autoreduction method to prepare plasmonic gold-embedded polypeptide micelles for synergistic chemo-photothermal therapy? Xingjie Wu,Linzhu Zhou,Yue Su,Chang-Ming DongJ. Mater. Chem. B, 2016,4, 2142-2152 10.1039/C6TB00198J
- [6] An AuNPs-functionalized AlGaN/GaN high electron mobility transistor sensor for ultrasensitive detection of TNT? Ying Li,Weirong Yao,Yunfei Xie,Renjun PeiRSC Adv., 2015,5, 98724-98729 10.1039/C5RA16704C
- [7] Ambient electrochemical NH3 synthesis from N2 and water enabled by ZrO2 nanoparticles? Tong Xu,Dongwei Ma,Chengbo Li,Qian Liu,Siyu Lu,Abdullah M. Asiri,Chun Yang,Xuping SunChem. Commun., 2020,56, 3673-3676 10.1039/C9CC10087C
- [8] An analyte-triggered artificial peroxidase system based on dimanganese complex for a versatile enzyme assay? Suji Lee,Min Su HanChem. Commun., 2021,57, 9450-9453 10.1039/D1CC03638F
- [9] An artificial photosynthetic system for photoaccumulation of two electrons on a fused dipyridophenazine (dppz)–pyridoquinolinone ligand? Philipp Traber,Stephan Kupfer,Stefanie Gr?fe,Isabelle Baussanne,Martine Demeunynck,Jean-Marie Mouesca,Serge Gambarelli,Vincent Artero,Murielle Chavarot-KerlidouChem. Sci., 2018,9, 4152-4159 10.1039/C7SC04348A
- [10] Achieving molecular stability of racemic 4-O-benzyl-myo-inositol-1,3,5-orthoformate through crystal formation? Richa Sardessai,Shobhana Krishnaswamy,Mysore S. ShashidharCrystEngComm, 2012,14, 8010-8016 10.1039/C2CE26199E
Journal Name：Journal of the Chemical Society A: Inorganic, Physical, Theoretical
research_products
-
CAS no.: 89640-58-4
![N-(3-cyanothiolan-3-yl)-2-[(2,2,2-trifluoroethyl)sulfanyl]pyridine-4-carboxamide](https://ossimg.kuujia.com/scimg/1444500/1444113-98-7x500.png)
![1,2,3,4,5,6-Hexahydro-[2,3]bipyridinyl-6-ol](https://ossimg.kuujia.com/scimg/1271000/1270529-38-8x500.png)
![2,2-Difluoro-3-[methyl(2-methylbutyl)amino]propanoic acid](https://ossimg.kuujia.com/scimg/2138500/2138166-62-6x500.png)
![2-(1H-indol-3-yl)-N-{[6-(thiophen-2-yl)-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]methyl}acetamide](https://ossimg.kuujia.com/scimg/2034500/2034271-14-0x500.png)