Synthesis and catalytic properties of arene complexes of ruthenium(II) prepared from Si, Zr, Ti and Al alkoxides by the sol-gel process

Journal of Materials Chemistry Pub Date: DOI: 10.1039/A802576B

Abstract
Methods of synthesizing materials for catalysis were developed by synthesizing eta;-arene complexes of ruthenium(ii) coordinated to vinylpyridine that was followed by sol-gel polymerization with 3-methacryloxypropyltriethoxysilane. To enforce sufficient catalytic properties, a series of hybrid materials from Si, Zr, Ti and Al alkoxides were prepared by co-condensation. The hydrolysis and polycondensation of materials were performed at different experimental conditions. The monomeric compounds were identified and catalytic activities were tested for cyclization of (Z)-3-methylpent-2-en-4-yn-1-ol to 2,3-dimethylfuran.
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