Aerosol-assisted chemical vapour deposition of silver films from adducts of functionalised silver carboxylates
Journal of Materials Chemistry Pub Date: 2003-01-14 DOI: 10.1039/B210085C
Abstract
A series of silver carboxylates containing unsaturated groups within the ![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
CH (3), H2CCHCH2CH2
(5), Me(H)CC(Me)
(8), Ph(H)CCH (11)], along with their CH (4), H2CCHCH2CH2
(6), Me(H)CC(Me)
(9), Ph(H)CCH (12)] and CHCH2CH2
(7), Me(H)CC(Me)
(10)]. The structures of 2, 6, 8 and 9 have been determined by single crystal X-ray diffraction; the adducts are all four-coordinate at silver with a chelating carboxylate, while 8 adopts a polymeric structure based on dimeric units and in which an approximately octahedral geometry at silver is attained by additional weak intermolecular Ag?O and π-Ag?CC interactions. Silver films have been grown by aerosol-assisted chemical vapour deposition using 6, 7, 9 and 10; no film was obtained with 2, while only a very thin film was generated by 12. Films grown from the sulfur-containing adducts 7 and 10 were rough and poorly reflective, while films from 6 and 9 were of superior quality, being smooth and highly reflective.
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Journal Name：Journal of Materials Chemistry
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CAS no.: 89640-58-4
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