A DFT study on direct benzene hydroxylation catalyzed by framework Fe and Al sites in zeolites?
Catalysis Science & Technology Pub Date: 2014-04-23 DOI: 10.1039/C4CY00369A
Abstract
Three-coordinated framework Fe sites in zeolites were theoretically demonstrated to show Lewis acidity and superior catalytic activity for the titled reaction compared with extra-framework Fe sites that were generally considered as the active species, while the corresponding Al sites are not reactive. This catalytic distinctness is ascribed to their divergent α-oxygen structures.
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Journal Name：Catalysis Science & Technology
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CAS no.: 89640-58-4
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