Rh-catalyzed sequential oxidative C–H activation/annulation with geminal-substituted vinyl acetates to access isoquinolines?
Chemical Communications Pub Date: 2015-07-14 DOI: 10.1039/C5CC04708K
Abstract
The concise synthesis of 3-substituted or non-C3-substituted isoquinolines through Rh-catalyzed sequential oxidative C–H activation/annulation with geminal-substituted vinyl acetates was developed with good functional group tolerance. The protocol was successfully applied to the total synthesis of the natural product papaverine.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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