Ligand-based reduction of nitrate to nitric oxide utilizing a proton-responsive secondary coordination sphere?
Chemical Communications Pub Date: 2017-09-26 DOI: 10.1039/C7CC06541H
Abstract
Utilizing the proton-responsive pyridinediimine ligand [(2,6-iPrC6H3)(N![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
CMe)(N(iPr)2C2H4)(NCMe)C5H3N] (didpa), the ligand-based reduction of nitrate (NO3?) to nitric oxide (NO) was achieved. The bioinspired [Fe(Hdidpa)(CO)2]+ was shown to react with tetrabutylammonium nitrate to form the dinitrosyl iron complex [Fe(didpa)(NO)2]+. The didpa scaffold was shown to provide two electrons for the net reduction of NO3? to NO in 43% yield.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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