Photoresponsive reversible self-assembly of rod-coil amphiphiles containing spiropyran groups?

Soft Matter Pub Date: 2023-01-18 DOI: 10.1039/D2SM01690G

Abstract

Stimuli-responsive assembly deformation is a key feature in constructing smart soft materials, which makes them versatile and autonomous. In this study, rod-coil amphiphilic compounds containing spiropyran (SP) groups were developed and synthesized to investigate their stimuli-responsive assembly in a solution system with 99% water content. In addition to photochromic phenomena, reversible light-mediated morphological alterations occurred in these molecular aggregates. Based on the different flexible chain segments of rod-coil amphiphiles, the initial assemblies underwent a dissociation–reassembly process under ultraviolet (UV) irradiation, whereupon they deformed or disassembled to assemblies. Furthermore, as the UV source was removed, the original nanostructures were gradually recovered again via the ring-closing reaction process. These compounds, interestingly, can selectively combine with copper ions to produce cross-linked co-assembled nanostructures. The copper ion complex solution of rod-coil amphiphilic compounds emitted unique bright blue fluorescence, which allowed for the specific visual identification of copper ions in aqueous solutions.

Graphical abstract: Photoresponsive reversible self-assembly of rod-coil amphiphiles containing spiropyran groups
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