Synthesis of isoindigo-derived conjugated polymers via ball-milling metal-free polymerization?
Polymer Chemistry Pub Date: 2022-12-07 DOI: 10.1039/D2PY01164F
Abstract
Herein, we report a ball-milling metal-free polymerization to synthesize isoindigo-derived conjugated polymers in the presence of readily available tris(diethylamino)phosphine. The resulting polymers possess comparable molecular weights and similar optical and electronic properties relative to their counterparts prepared via the solvent method. This new solvent-free and metal-free polymerization method can be performed under ambient conditions.
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Journal Name：Polymer Chemistry
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CAS no.: 89640-58-4
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