Visible-light-driven photoredox-catalyzed C(sp3)–C(sp3) cross-coupling of N-arylamines with cycloketone oxime esters?
Organic Chemistry Frontiers Pub Date: 2022-03-24 DOI: 10.1039/D2QO00128D
Abstract
A novel photoredox-catalyzed C(sp3)–C(sp3) cross-coupling between N-arylamines and cycloketone oxime esters under mild conditions has been accomplished. The redox-neutral reaction proceeds with good functional group tolerance and excellent regioselectivity without any extra base or ligand control. In addition, this approach was successfully applied for the late-stage modification of short peptides and analogues.
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Journal Name:Organic Chemistry Frontiers
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CAS no.: 89640-58-4