Synthesis of diverse unsymmetric 1,4-adducts via a three-component coupling reaction of malonate derivatives, [60]fullerene and electrophiles/nucleophiles?
Organic Chemistry Frontiers Pub Date: 2023-02-14 DOI: 10.1039/D3QO00078H
Abstract
A three-component coupling reaction of malonate derivatives, [60]fullerene, and electrophiles/nucleophiles has been developed as a facile and efficient method to access various 1,4-unsymmetric malonate functionalized [60]fullerenes. This methodology features low cost, simple operation, transition metal-free nature and a wide range of substrates.
![Graphical abstract: Synthesis of diverse unsymmetric 1,4-adducts via a three-component coupling reaction of malonate derivatives, [60]fullerene and electrophiles/nucleophiles](http://scimg.chem960.com/usr/1/D3QO00078H.jpg)
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Journal Name：Organic Chemistry Frontiers
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CAS no.: 89640-58-4
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