Visible-light induced three-component reaction for α-aminobutyronitrile synthesis by C–C bond formation using quantum dots as photocatalysts?
Organic & Biomolecular Chemistry Pub Date: 2022-12-06 DOI: 10.1039/D2OB01797K
Abstract
We describe a three-component reaction of malononitrile, benzaldehyde and N,N-dimethylaniline using aluminium doped CdSeS/CdZnSeS(Al)/ZnS quantum dots (QDs) as visible light catalysts to synthesize α-aminobutyrilitriles at room temperature and under mild conditions. The reactions exhibit high functional group tolerance, and the well dispersed quantum dot catalysts are highly efficient with a turnover number (TON) greater than 1.1 × 103 and can be recycled at least three times without significant loss of catalytic activity.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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