Base-mediated synthesis of cyclic dithiocarbamates from 1-amino-3-chloropropan-2-ol derivatives and carbon disulfide?
Organic & Biomolecular Chemistry Pub Date: 2023-07-18 DOI: 10.1039/D3OB01070H
Abstract
An efficient method for the preparation of six-membered cyclic dithiocarbamates is described, in which triethylamine effectively promotes the reaction of 1-amino-3-chloropropan-2-ol derivatives with carbon disulfide. On the basis of the experimental and theoretical studies, a reaction mechanism is proposed to explain the difference between the present reaction and our previously reported carbon dioxide fixation.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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