An iodine-mediated new avenue to sulfonylation employing N-hydroxy aryl sulfonamide as a sulfonylating agent?
Organic & Biomolecular Chemistry Pub Date: 2021-04-12 DOI: 10.1039/D1OB00036E
Abstract
A novel and highly efficient I2/K2CO3 mediated regioselective sulfonylation of thiophenols, aryl acetylenic acid and aromatic alkynes with N-hydroxy sulfonamide has been developed. N-hydroxy sulfonamide has been used for the first time for the synthesis of these sulfones. The scope and versatility of the reaction has been demonstrated by the regio- and stereoselective synthesis of different analogs of sulfones with various structural features.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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