Redox-switchable bistable nickel corrole?

Inorganic Chemistry Frontiers Pub Date: 2023-04-20 DOI: 10.1039/D3QI00294B

Abstract

Stable porphyrinoid-based radicals and diradicaloids that possess delocalized π-systems can be highly advantageous for use in spintronic and electronic applications. In this work, we present the facile synthesis of a neutral 17π-electron nickel corrole monoradical with a SOMO–HOMO degenerate electronic configuration. The one-electron oxidation of this radical produces an open-shell corrole cation—a unique 16π-electron Hückel antiaromatic singlet diradicaloid. The 16/17π redox species are highly air-stable and reversibly switchable with a moderate redox potential. At various spin and oxidation states, this corrole shows multi-level aromaticity switching behavior according to Hückel or Baird's law. The coexisting counter-rotating diatropic and paratropic ring currents are evaluated for the neutral radical. This work establishes nickel corroles as a promising platform for supporting stable open-shell π-conjugated systems with facile tunable aromaticity.

Graphical abstract: Redox-switchable bistable nickel corrole
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