Assembly of symmetrical and unsymmetrical platinum(ii) rollover complexes with bidentate phosphine ligands?

Dalton Transactions Pub Date: 2014-08-06 DOI: 10.1039/C4DT02080D

Abstract

The reaction of the cyclometalated rollover complex [Pt(bpy-H)(Me)(DMSO)] (bpy-H = cyclometalated 2,2′-bipyridine) with two diphosphines, dppm (1,1-bis(diphenylphosphino)methane) and dppe (1,2-bis(diphenylphosphino)ethane), was investigated. According to the reaction conditions, dppm behaves as a monodentate, bridging or chelated ligand, whereas dppe gave only chelated species. Some aspects of the reactivity of the isolated species were studied, including protonation with [H3O·18-crown-6][BF4] and coordination reactions of mononuclear complexes, obtaining, inter alia, rare examples of unsymmetrical organometallic species with bridging dppm.

Graphical abstract: Assembly of symmetrical and unsymmetrical platinum(ii) rollover complexes with bidentate phosphine ligands
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