Assembly of a calix[4]arene-supported MnIIIMnII cluster mediated by halogen interactions?

CrystEngComm Pub Date: 2014-06-26 DOI: 10.1039/C4CE00729H

Abstract

A new calix[4]arene-supported MnIIIMnII cluster, formed by the introduction of 3,5-dichlorobenzoate to a system known to afford MnIII2MnII2 Single-Molecule Magnets (SMMs), assembles in a layered manner through halogen interactions; structural and magnetic properties of this new cluster are presented.

Graphical abstract: Assembly of a calix[4]arene-supported MnIIIMnII cluster mediated by halogen interactions
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