A 5.3 nm giant metal–organic cage and its supramolecular gel for the formation of dye molecular ionic pairs?
Dalton Transactions Pub Date: 2023-03-13 DOI: 10.1039/D3DT00189J
Abstract
A terpyridine-based supramolecular cage was successfully synthesized by the self-assembly of a hexapodal metal–organic ligand with Zn2+. This metallo-cage exhibited two large parallel planes on the top and bottom with diameters close to 6 nm and a face-to-face distance close to 3.5 nm, thus possessing a large cavity. Electrospray ionization mass spectrometry (ESI-MS), nuclear magnetic resonance (NMR), two-dimensional nuclear Overhauser (2D-NOESY), and diffusion-ordered (DOSY) spectroscopies as well as transmission electron microscopy (TEM) and atomic force microscopy (AFM) measurements, unambiguously supported the formation of a supramolecular cage. Furthermore, the corresponding metal–organic gel was felicitously prepared in CH3CN/H2O and displayed good adsorption performance for dye molecules.
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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