C10H6NO2Cd(NO3)·2H2O: a birefringent crystal with an enlarged band-gap derived from covalent edge-sharing connection?
Dalton Transactions Pub Date: 2023-04-05 DOI: 10.1039/D3DT00688C
Abstract
A new birefringent crystal, C10H6NO2Cd(NO3)·2H2O, was designed by combining a π-conjugated [C10H6NO2]? group with a CdO7N polyhedron. Notably, the experimental energy gap is 0.02 eV higher than that of the organic raw material, which resulted from a covalent edge-sharing connection, implying a new strategy to improve the band-gap of birefringent materials.
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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